Predict The Organic Product Of The Following Reaction H2so4

Some examples follow: Conversely, since E1 reaction products are almost always accompanied by S N 1 reaction products, they are almost never used in organic synthesis. Hydrogenation of an alkene using hydrogen gas and a platinum (or palladium or nickel) catalyst. What is the major organic product obtained from the following reaction? II Which will be the product formed when the following compound is treated with HNO3 and H2SO4?. If the rate of each possible elimination was the same, we might expect the amounts of the isomeric elimination products to reflect the number of hydrogens that could participate in that reaction. But equally it could be any one of a large number of other compounds all of which can be oxidised by manganate(VII) ions under. The compound below has been isolated from the safflower plant. 79) 80)Provide the major organic product of the. Draw your answer in skeletal form. can 2-butyne be an only product from using sulfuric acid, mercuric sulfate. 2-hexanol Na2Cr2O7 H2SO4, H2O 1-hexanol 2-chlorohexane O 2-hexanone O hexanal O hexanoic acid Get more help from Chegg Get 1:1 help now from expert Chemistry tutors. Milder oxidation may change a primary alcohol into an aldehyde, a secondary alcohol into a ketone, etc. Questions are typically answered within 1 hour. The products of its reaction with 1) meta-chloroperoxybenzoic acid, 2) KMnO 4 in aqueous acid and 3) O 3, followed by Zn in acetic acid, are to be given. When drawing hydrogen atoms on a carbon atom, either include all hydrogen atoms or none on that carbon atom, or your structure may be marked incorrect. Furthermore, it can find the coefficients for only just hypothetically possible reactions. Indicate proper stereochemistry where necessary. Sample Problems 8. For the following reaction, select a correct product characterization from the response list. B) Reactions involving only achiral or racemic materials must produce achiral or racemic. The three product types are IEPOX pathway (IEPOX + 2-methyltetrol + IEPOX organosulfate) (blue), glyoxal and its dark reaction products (red), and organic acids (green). This equation is balanced because on both sides there are 8 carbon atoms, 20 hydrogen. Reactions with PCl 5 probably give an iminochloride, and this in turn is hydrolyzed to the same amide. A Predict the major mono-alkylation products you would expect to obtain from reaction of the following substances with chloromethane arid AlCl3: (a) Bromobenzene (b) m-Bromo-phenol (c) p-Chloro-aniline (d) 2, 4-Dichloronitrobenzene (e) 2, 4-Dichlorophenol (f) Benzoic acid (g) p-Methyl benzenesulfonic acid (h) 2, 5-Dibromotoluene. The starting material is (ch3)2C=NHch2ch3. Draw the major organic product that is produced in the following reaction. Here is a list of topics: 1. 49) When H2NCH2CH2CH2CH2COCH3 is heated in the process of an acid catalyst, a reaction occurs. What is the major organic product obtained in the following reaction? A. C H O H 2N C H ++N H O CC H O H 3C C H CC H 2O O O H ++ Predict the organic products formed in the following condensation reactions of benzaldehyde. However on 1 there is no reaction considering silver is scale down within the endeavor series that copper and lithium ( identical goes for 7). The (R) or (S) appellation control each stereonature carbon bit is bounded nigh to the exculpation pummel, please entice the fruits suitably. name: Achiral (Common pinacolone) CH H3 O OH CH3 CH3 2,3-Dimethyl-2,3-butanediol Water (Common name: pinacol) B. 37 A C 8 H 14 hydrocarbon (X) is reduced by sodium in liquid ammonia to a single C 8 H 16 product (Y). Draw the major organic product formed in the following reaction. If oxidation occurs, the orange solution containing the dichromate(VI) ions is reduced to a green solution containing chromium(III) ions. Be sure to indicate the proper stereochemical. In this reaction, the water molecule will behave like a hydrogen halide to the alkene which gives the addition product this reaction is known as a hydration reaction. HBr (1 equivalent) C CH 19) Provide the structure of the major organic product(s) in the reaction below. 10 The S N 2 reaction of 1-chloro-3-methylbutane with sodium methoxide is relatively slow, but can be accelerated by the addition of a. Milder oxidation may change a primary alcohol into an aldehyde, a secondary alcohol into a ketone, etc. 5) Draw the complete electron pushing mechanism for the second reaction in question 4. None of the choices. HO H2SO4 A) I B) II C) III D) IV Which of the following compounds has the highest boiling point? A) I B) II C) III D) IV 9:09 AM Mon Apr 29 ゃしダ46% f) What is the major organic product obtained from the following reaction?. Reactions of Haloalkanes, Alcohols, and Amines. This is important in predicting SN1/SN2 reactions down the road. If oxidation occurs, the orange solution containing the dichromate(VI) ions is reduced to a green solution containing chromium(III) ions. Predict the product(s) for each of the following reactions. Predict the product for each acid-catalyzed hydration of the alkene reaction. Be sure to indicate stereochemistry where appropriate and to include stereoisomers if any. The answer to "Predict the products of the following acidbase reactions. With around-the-clock expert help and a community of over 250,000 knowledgeable members, you can find the help you need, whenever you need it. Draw the skeletal structure of the major organic product of the following reaction. product predominates. Provide the structure of the major product which results from 1,4-addition of Br2 to the diene shown below. Chemistry Organic GOC Reaction Mechanism Elimination E1 E2 E1cB Elimination reactions Alkyl halides E1 vs E2 Saytzev Rule Zaitsev Rule. Be sure to include stereochemistry where appropriate. * Study and know the good leaving group ( important). Chemistry Organic GOC Reaction Mechanism Elimination E1 E2 E1cB - Free download as PDF File (. png 778×457 26. If a double replacement reaction forms a precipitate, CIRCLE the precipitate. * the most stable product is the major product. propanal (older name: propionaldehyde). Be sure to indicate stereochemistry where appropriate and to include stereoisomers if any. * select the most electrophile and the most nucleophil. Answer: Diff: 2 Section: 14. A Predict the major mono-alkylation products you would expect to obtain from reaction of the following substances with chloromethane arid AlCl3: (a) Bromobenzene (b) m-Bromo-phenol (c) p-Chloro-aniline (d) 2, 4-Dichloronitrobenzene (e) 2, 4-Dichlorophenol (f) Benzoic acid (g) p-Methyl benzenesulfonic acid (h) 2, 5-Dibromotoluene. University. OH N Cl S O CH3 O 2. Begin Share Embed. Predict the organic product of the following reaction and include hydrogen atoms in your structure: Posted one year ago. CCH Sia2BH H2O2 OH-21) Provide the structure of the major organic product(s) in the reaction below. In the addition of HBr to conjugated dienes, is the product which results from 1,2-addition or that which results from 1,4-addition typically the product of kinetic control?. Hydrohalogenation. Place the letter corresponding to the term in the blank to the left of. Provide proper IUPAC names for each of the following compounds or structures for each of the following names of organic compounds as appropriate. Consider the following E2 reaction. 15 Name the following alkynes, and predict the products of their reaction with (i) H2 in the presence of a Lindlar catalyst and (ii) H3O + in the presence of HgSO 4: HC C C H2 C H3C CH3 H2C CH3 C CC H2 HC CH3 H3 CH2 CH H3C CH3 (a) (b) Solution:. * the most stable product is the major product. A) CH3OH B) H2O C) HCN D) KCN E) KOtBu 31. Draw all stereoisomers that are formed. propanal (older name: propionaldehyde). I understand when we do the dehydration using H2SO4 which acts. If oxidation occurs, the orange solution containing the dichromate(VI) ions is reduced to a green solution containing chromium(III) ions. CH3CH2CH2CH2Br 1. Provide the structure of the major product which results from 1,2-addition of HBr to the diene shown below. When appropriate, be sure to indicate stereochemistry. b) Ethanal. check_circle Expert Answer. Answer: View Answer. Predict the organic products for the following reaction. Organic, inorganic, analytical, etc. gnment ProplemiD=123362446 ct/itemView ic Chemistry Summer 2019 CHE 2230 and 2240 Part A Predict the organic products of the following reaction: H2SO4, heat CH3 CH2 CH-CH OH Draw the molecule(s) on the canvas by choosing buttons from the Too The single bond is active by default. (You don't do this in this lab). B) II and III. draw a stepwise, detailed mechanism for the following reaction. 79) 80)Provide the major organic product of the. Consider the following E2 reaction. Questions and answers covering Chapter 9 (E1/E2 reactions) assigned by Dr. What is the major organic product that is formed from the reaction on the right? H2SO4 но 3 ОН Он ОН HO C) 3 A) 1 B) 2 D) 4. D) Enantiomers exhibit equal and opposite optical rotations. propanoic acid. Cross one out or graded in order. (a) Friedel-Crafts Acylation, CH3 is o,p director (b) benzylic substitution (c) reaction thru benzyne intermediate (d) Nucleophilic Aromatic Substitution (e) o,p directed electrophilic aromatic substitution. Include the states of all reactants and products. CCH Sia2BH H2O2 OH-21) Provide the structure of the major organic product(s) in the reaction below. A rigorous proof of the configurational inversion that occurs at the substitution site in S N 2 reactions makes use of such reactions. C) III and IV. Ma 1) CH3MgCl (excess) Et20 2) H30 Complete the mechanism for the above reaction below. Depending on the work up, different products may be isolated: reductive work-up gives either alcohols or carbonyl compounds, while oxidative work-up leads to carboxylic acids or ketones. Identify the family (type) of each organic compound and write its IUPAC name. The aldol reaction is a means of forming carbon–carbon bonds in organic chemistry. First of all, an elimination reaction is a type of organic reaction in which two substituents are removed from a molecule in either a one or two-step mechanism. Problem: Acid-catalyzed dehydration of 3-methyl-2-butanol gives three alkenes: 2-methyl-2-butene, 3-methyl-1- butene, and 2-methyl-1-butene. Two SN1 products are possible, three E1 products are also possible. 26d: Propanone could also be formed from propene by reaction with steam over an acidic catalyst, 13N. The chemical compounds of living things are known as organic compounds because of their association with organisms and because they are carbon-containing compounds. 49) When H2NCH2CH2CH2CH2COCH3 is heated in the process of an acid catalyst, a reaction occurs. The acid-catalyzed dehydration of 2-methylcyclohexanol to form a mixture of cyclic alkenes has become a standard experiment in the organic chemistry and upper-level laboratory curricula at several colleges and universities (1-4). We'll look at the reaction with ethene. 07 M KOH in a coffee-cup calorimeter at 23. Predict the major organic product in the following reactions and classify the type of addition reaction it is (syn vs anti, Markovnikov vs anti-Markovnikov, it can be multiple of these). Predict the organic product that is formed when the ion shown below is treated with an excess of {eq}H_2SO_4 {/eq}. CH3CH2CH2CH2Br 1. Predict the major organic product in the following reactions and classify the type of addition reaction it is (syn vs anti, Markovnikov vs anti-Markovnikov, it can be multiple of these). If you consult a pKa table§, then you will find that protonated organic alcohols typically have pKa values around -2, while H₃O⁺ has a pKa of -1. As the product, 1-pentanone is given. Background. Major Organic Products Given the major organic product(s) of each of the following reactions. Sodium hydroxide (NaOH) is a base, so when it reacts with sulfuric acid (H2SO4), what we'll see is what is called an acid-base reaction. Et0H, EtONa, 60 oc 2a. Good question! One way to think about this is as an acid-base equilibrium with competition between two acids - H₃O⁺ and the protonated 2-methylpentan-2-ol. Answer: Type: SA Section: 17-7 48) What class of organic compounds results when cyclopentanone reacts with ethylamine in the presence of trace acid? A) cyanohydrin B) semicarbazone. With reaction #2, on the other hand, we can say that it undergoes a concerted mechanism. When drawing hydrogen atoms on a carbon atom, either include all hydrogen atoms or none on that carbon atom, or your structure may be marked incorrect. 2-cyclopentylethanol reacts with H2SO4 at 140degrees C yields? please help me draw the structure. Carolyn Straub. 50 M H2SO4 according to the following reaction. following reactions, showing the main organic products. For the alcohol reaction below, give the major organic product. 97) Predict the major organic product resulting from the following sequence of reactions. The proton NMR spectrum of A shows a complex multiplet at δ = 7. The mechanism of syn addition of the hydrogens. Compound A, C 8H 10, yields three monobromo substitution products (one major, two minor), C 8H 9Br, on reaction with bromine in the presence of iron. Letter grades will be assigned on the following basis. Sample Problems 8. Elimination Reactions 10. Predict the organic product(s) of the following reaction. (i) In the boxes below, draw the structures of the zwitterions formed from this section of the protein. Grades are not curved. When we predict the major organic product formed when the coumpound underoes a reaction with EtONa - CH3CH2C(Br)(CH3)CH3, the prediction will be CH3C = CC(CH3)2. For instance quantity 1, 7 and 10 have a complete of two separate molecules (where one is by myself and the other is a compound). As such, bond dissociation energies are imperfect indicators of energy changes in a reaction. The major product for the following reaction is: (B) Markovnikov rule (more stable carbocation intermediate) 8. Here is a list of topics: 1. 58)Provide the structure of the major organic product(s) in the following reaction. 55)Provide the structure of the major organic product in the following reaction. I did not draw your product, but you can see the mechanism and thus predict the product yourself. When drawing hydrogen atoms on a carbon atom, either include all hydrogen atoms or none on that carbon atom, or your structure may be marked incorrect. Test Difficulty : Average Time Spent: 12 mins. Studyres contains millions of educational documents, questions and answers, notes about the course, tutoring questions, cards and course recommendations that will help you learn and learn. 40) Draw the major organic product generated in the reaction below. com - View the original, and get the already-completed solution here!. The mechanism of syn addition of the hydrogens. Solution: The reactant is symmetrical, so OH adding to either of the carbon that is double bonded will yield the same product. But if the reaction is found to be impossible for mathematical reasons one can be sure that it cannot occur in a test tube: H. 24: Predict the product(s) and provide the complete mechanism for each. When mixtures of products are expected, indicate the relative amounts of each. However, the chemistry of these two functional groups is very different. Thank you for your assistance. ---> The structure I. 2-butyne is symmetrical around the triple bond. If there is no reaction say NR. Organic, inorganic, analytical, etc. 9 Predict the major products of the following reactions: (a) Mononitration of bromobenzene (b) Monobromination of nitrobenzene (c) Monochlorination of phenol (d) Monobromination of aniline Solution: (a) It will be o, p orientation, but because of spacial effect, the p orientation product will be the major product. Assume each is in the most appropriate solvent. Part A Predict the organic products of the following reaction: H2SO4, heat CH3 CH2 CHCH3 OH Draw the molecule(s) on the canvas by choosing buttons from the Tools (for bonds), Atoms, and Advanced Template toolbars. When appropriate, be sure to indicate stereochemistry. Each organic product has its pH adjusted to its isoelectric point to form a zwitterion. Provide a name for the compound below. Answer to Predict the organic product of the following reactionsand include hydrogen atoms in your structure. 6) 7)Provide the structure of the major organic product in the reaction below. 97) Predict the major organic product resulting from the following sequence of reactions. Draw the by-products of the reaction and use curved arrows to show the movement of electrons. Dehydration of 2-methyl-2-pentanol forms one major and one minor organic product. Under kinetic reaction control, one or both forward reactions leading to the possible products is significantly faster than the equilibration between the products. Alkenes and Alkynes. The group that is anti to oxygen migrates in the pinacol rearrangement of the diol shown. Explain the mechanism for this reaction using curly arrows to represent the movement of electron pairs and explain clearly why only one organic product is formed. 57)Provide the structure of the major organic product in the following reaction sequence. If more than one product is possible, indicate which would be the major product. 24: Which nitrogen atom in the following compound is most basic? Explain. Reactions with PCl 5 probably give an iminochloride, and this in turn is hydrolyzed to the same amide. The pKa is derived from the equilibrium constant for the acid's dissociation reaction, Ka, and uses a logarithmic scale to allow the pKa values to […]. (1) Predict the major product from each reaction. Give simple chemical tests to distinguish between the following pairs of compounds. [2] The concentration of $^-OC(CH_3)_3$ is decreased. None of the choices. I think the correct answer from the choices listed above is option B. These phenomena reflect the relative influences of thermodynamic vs. If a double replacement reaction forms a precipitate, CIRCLE the precipitate. If oxidation occurs, the orange solution containing the dichromate(VI) ions is reduced to a green solution containing chromium(III) ions. Predict the organic product(s) of the following reaction. The reaction between alkanes and fluorine: This reaction is explosive even in the cold and dark, and you tend to get carbon and hydrogen fluoride produced, rather than the desired substitution reaction. (CH3)3CCH2CH2OH Na2Cr2O7 H2SO4 → 7) 8)Provide the structure of the major organic product in the reaction below. 45) Draw all likely products of the following reaction and circle the product you expect to predominate. All Organic Chemistry Resources. 535 M H2SO4 is added to 20. Brz H2O Ye Boh OH HO Br A) I B) II C) III D) IV Predict the major product of the following reaction. Draw the organic products in each of the following. Question: Predict The Neutral Organic Product Of The Following Reaction. Predict the products of reaction of pent-1-yne with the following reagents. d) Propanal. Predict the major organic product in the following reactions and classify the type of addition reaction it is (syn vs anti, Markovnikov vs anti-Markovnikov, it can be multiple of these). Predict the product for the following reaction: When drawing hydrogen atoms on a carbon atom. If the rate of each possible elimination was the same, we might expect the amounts of the isomeric elimination products to reflect the number of hydrogens that could participate in that reaction. Alkene is reaction with water in the presence of sulfuric acid, first step is proton ( H + ) addition to the double bond which forms carbocation (more stable carbocation) followed. Dehydration of 2-methyl-2-pentanol forms one major and one minor organic product. 2) Determine the major organic product for the following reaction scheme. The primary reaction types students encounter are displacement, acid-base and combustion. In (a) and (b) the Markovnikov product is the major product and is the one shown. These differences of perception can be attributed to factors such as age, sex. (HI behaves as an HX reagent. What is the molecular formula for this natural product? 5. This means that the protonated alcohol is a slightly stronger acid and thus the. (All hydrogen atoms are implied. What is the major organic product obtained in the following reaction? A. Good question! One way to think about this is as an acid-base equilibrium with competition between two acids - H₃O⁺ and the protonated 2-methylpentan-2-ol. Indicate the structure of the major organic product in each of the following reactions. Predict the major organic product of the following reaction. When drawing hydrogen atoms on a carbon atom, either include all hydrogen atoms or none on that carbon atom, or your structure may be marked incorrect. HBr (1 equivalent) C CH 19) Provide the structure of the major organic product(s) in the reaction below. The first step---identifying the type of reaction involved---is usually the most difficult. Predict the major organic product in the following reactions and classify the type of addition reaction it is (syn vs anti, Markovnikov vs anti-Markovnikov, it can be multiple of these). 40) Draw the major organic product generated in the reaction below. The primary reaction types students encounter are displacement, acid-base and combustion. The general form of the S N 2 mechanism is as follows: nuc: = nucleophile X = leaving group (usually halide or tosylate) The S N 2 reaction involves displacement of a leaving group (usually a halide or a tosylate), by a nucleophile. Complete the following reactions by giving the structures of the principal organic products. Fill in the reagents in their respective boxes above the arrows for the following reactions. Provide structure(s) for the starting material(s), reagent(s) or the major organic product(s) of each of the following reactions or sequences of reactions. Reactions with PCl 5 probably give an iminochloride, and this in turn is hydrolyzed to the same amide. If acid and heat are added after the reaction has occurred, what product would be produced? 36. Thanks! Use the activity series to predict whether the following reaction will occur. Play this game to review Organic Chemistry. a) dilute hydrochloric acid in the presence of lipase. The products are salt and water. In each reaction, an excess of benzaldehyde is used. Predict the organic product of the following reaction and include hydrogen atoms in your structure. 2-cyclopentylethanol reacts with H2SO4 at 140degrees C yields? please help me draw the structure. What is the major organic product obtained in the following reaction? A. Which reagent(s) give some type of cyclopropane ring as product when reacted with an alkene? (A) CH2N2 & Heat (B) CH2I2 & Zn(Cu) (C) CHBr3 & KOH (D) CHCl3 & t-BuO-(E) All of these 15. 24: Which nitrogen atom in the following compound is most basic? Explain. Organic chemistry reaction question given diels-alder product, ID diene and dien Help draw the major product with the correct stereochemistry. Write balanced chemical reactions for the following combustion reactions. Acid + alohol = an ester + H2O. Brz H2O Ye Boh OH HO Br A) I B) II C) III D) IV Predict the major product of the following reaction. Include hydrogen atoms in your structure. More than one equivalent of H2 + Pd/C reduces the alkyne all the way to an alkane. Draw the structure of each organic product in the boxes. 6 Diagnostic Tests 179 Practice Tests Question of the Day Flashcards Learn by Concept. The ratio of acid to aldehyde will depend on the temperature of the reaction and the concentration of the oxidant: the more concentrated the oxidant is, the greater the ratio of. 2-hexanol Na2Cr2O7 H2SO4, H2O 1-hexanol 2-chlorohexane O 2-hexanone O hexanal O hexanoic acid Get more help from Chegg Get 1:1 help now from expert Chemistry tutors. 1 Answer to Predict the products from reaction of 5-decyne with the following reagents: (a) H2 Lindlar catalyst (b) Li in NH3 (c) 1 equiv Br2 (d) BH3 in THF, then H2O2, OH- (c) H2O, H2SO4, HgSO4 (f) Excess H2, Pd/C catalyst - 389478. Finding coefficients for chemical reactions is often complicated, especially in the case of redox processes. Reactions of 1-Methylcyclohexene and Other Alkenes. (Z)-3-hexene + mCPBA A) I B) II C) III D) IV. Draw the correct structure of the expected product of the following reaction. Several alkyl halides, including. 5) Explain why the presence of a weak base / nucleophile favors E1 reactions over E2. Fundamentals General mechanism of the halogenation reaction:- Step 1 As the halogen molecules approach the. Remember, "no reaction may be an answer. Chemistry Organic GOC Reaction Mechanism Elimination E1 E2 E1cB - Free download as PDF File (. Alkene is reaction with water in the presence of sulfuric acid, first step is proton ( H + ) addition to the double bond which forms carbocation (more stable carbocation) followed. 24: Predict the product(s) for each reaction below and provide the comp 24. Predict the products of the following reaction. Get 1:1 help now from expert Chemistry tutors. Show the products for the reaction with HgSO4/H2SO4/H20. If you can't find your institution, please check your spelling and do not use abbreviations. Google Classroom Facebook Twitter. (You don't do this in this lab). gnment ProplemiD=123362446 ct/itemView ic Chemistry Summer 2019 CHE 2230 and 2240 Part A Predict the organic products of the following reaction: H2SO4, heat CH3 CH2 CH-CH OH Draw the molecule(s) on the canvas by choosing buttons from the Too The single bond is active by default. in cases where there is more than one answer, just draw one. (10 points) Predict the major organic product or products for each of the following. 50) Provide the structure of the major organic product which results when benzaldehyde reacts. Identify the two products by writing accurate structures for each. 49) When H2NCH2CH2CH2CH2COCH3 is heated in the process of an acid catalyst, a reaction occurs. Predict the neutral organic product of the following reaction. Show transcribed image text Predict the organic and inorganic products of the following reaction and select the class to which the product belongs. The initial rate of reaction was measured as a function of the concentration of A. Solution: The following compounds are treated with HNO3/H2SO4. what is/are the organic product(s) in the reaction below. Chemistry Organic GOC Reaction Mechanism Elimination E1 E2 E1cB Elimination reactions Alkyl halides E1 vs E2 Saytzev Rule Zaitsev Rule. 3) Predict the major product of the following reaction. D) I and III. Calculate H of this reaction per mole of H2SO4 and KOH reacted. If you can't find your institution, please check your spelling and do not use abbreviations. Remember, "no reaction may be an answer. Problem- Predict the organic products of the following reaction. name: Achiral (Common pinacolone) CH H3 O OH CH3 CH3 2,3-Dimethyl-2,3-butanediol Water (Common name: pinacol) B. O Cl CH3 NO2 F3C Br H NaNH2/NH3 H2O H2O O HO CH 3 NO2 HO Cl O HO CH 3 NO2 F3C NH2 F3C NH 2 F3C F3C NH2 F3C NH 2 a) dil. Show each and every step. And we don't have any charge here, so it's in a neutral state. If you expect no reaction, indicate. (If no reaction, draw the starting material. I have provided a screenshot of the reactants. exam multiple choice bank: lecture alkynes oxidizing agent, base reducing agent, base what is/are the major organic product(s) of the following reaction? in the. b) sodium hydroxide. Concept introduction: When alkenes react with meta -chloroperoxybenzoic acid, oxygen atom adds to the double bond to give epoxides. Predict the product of the following reaction. Predict the major organic products of the following reaction: E1 to give alkene, more substituted. B) 4-methyl-1-pentene. Another side reaction that occurs is oxidation of the 1 -butanol by either H2SO4 or Br + (formed by oxidation of Br- by H2SO4). Solution: The following compounds are treated with HNO3/H2SO4. Predict the two major organic products of the following reaction. Answer: aromatic Question 25 (2 points) Provide the major organic product(s) when benzene is treated with the following sequence of. Markovnikov's rule is needed to predict the major organic product. b) ethanoic acid with propan-2-ol. When appropriate, be sure to indicate stereochemistry. B) 4-methyl-1-pentene. Draw the organic products of the following reaction. Which reagent(s) give some type of cyclopropane ring as product when reacted with an alkene? (A) CH2N2 & Heat (B) CH2I2 & Zn(Cu) (C) CHBr3 & KOH (D) CHCl3 & t-BuO-(E) All of these 15. Make sure to consider stereochemistry & regiochemistry, if applicable. A compound with molecular formula C 3 H 8 O has a strong absorption at 3600 cm -1 in the infrared spectrum. 10: Methyl vinyl ketone (structure below) was treated with HBr, and the product isolated and analyzed by 1 H NMR. Perceptions of Reality in the Matrix Essay The question of ‘reality’ has always intrigued people throughout the world. [1+1] (c) Y. Be sure to indicate the major product if more than one product is formed. Draw the major organic product that is produced in the following reaction. If acid and heat are added after the reaction has occurred, what product would be produced? 36. Employing theoretical methods for chemical prediction: a none. The E2 Reaction. Concepts and reason Alcohols undergo a dehydration reaction when the react with concentrated acids in the presence of heat. d) butanoic acid with butan-1-ol. What happens to the reaction rate with each of the following changes? [1] The solvent is changed to DMF. 24: Name the following amine, including R,S stereochemistry, and draw t 24. Instructor: Dr. Why? Because the alkyl group is considered to be activating, so the product of the first alkylation will be more reactive than the initial reactant and may then undergo further a. 4) Each compound below undergoes a Dieckmann Condensation (Intramolecular Claisen). 23 Predict the products of the following reactions (the aromatic ring is unreactive in all cases). CH3OH, H2SO4 the product isolated is: • A) propanal B) propanoic acid • C) propanolD) methyl propanoate. Another side reaction that occurs is oxidation of the 1 -butanol by either H2SO4 or Br + (formed by oxidation of Br- by H2SO4). The only difference is that we shift an alkyl group rather than shift a proton, while still undergoing various intermediate steps to furnish its final product. ) 5 Alkyne Hydration Reaction. ) CH3C=C-CH3 + Br2 +44 141 628 6080. The ratio of acid to aldehyde will depend on the temperature of the reaction and the concentration of the oxidant: the more concentrated the oxidant is, the greater the ratio of. The product mixture would therefore consist of 2 pairs of enantiomers, which are constitutional isomers of each other. 98 KB prasanna November 4, 2016, 7:24am #2 Complete the following reactions by giving the structures of the principal organic products. Be sure to indicate the correct relative stereochemistry (i. (NYSE:CTLT) Q3 2020 Earnings Conference Call May 5, 2020 08:15 ET Company Participants Paul Surdez - Vice President, Investor Relations John Chim. 40) Draw the major organic product generated in the reaction below. If you're behind a web filter, please make sure that the domains *. Draw all stereoisomers that are formed. Since the volatility of an organic compound in the atmosphere can change by reactions in the gas phase (Section 2) and reactions in the particle phase (Section 3), over the course of several generations of oxidation (Section 4), the reaction scheme underlying SOA formation is probably something like that shown in Fig. CHE-310 Organic Chemistry I. Find the training resources you need for all your activities. The Mechanism of the Paterno-Buchi Reaction and its Application in the Organic Synthesis Review The Paternò–Büchi reaction, named after two chemists who established its basic utility and form, is a photochemical reaction that forms four-membered oxetane rings from a carbonyl and an alkene. (Assume that PCC is present in excess. Explain why a more stable alkyne (2-butyne) is isomerized to a less stable alkyne (1-butyne), but under similar conditions, 2,5-dimethyl-3-hexyne forms 2,5-dimethyl-2,3-hexadiene. Brz H2O Ye Boh OH HO Br A) I B) II C) III D) IV Predict the major product of the following reaction. 10 to specific alkyl halides. When appropriate, be sure to indicate stereochemistry. Predict the MAJOR product of the following reaction: 2,3-dimethylcyclohexanol + H 2 SO 4 A) B) C) D) E) Page 9 13. Concept introduction: When alkenes react with meta -chloroperoxybenzoic acid, oxygen atom adds to the double bond to give epoxides. An aromatic hydrocarbon is formed. Predict the structures of A and B in the following reaction: The importance of sulfonate esters as intermediates in many substitution reactions cannot be overstated. 2-butyne is symmetrical around the triple bond. The ratio of acid to aldehyde will depend on the temperature of the reaction and the concentration of the oxidant: the more concentrated the oxidant is, the greater the ratio of acid to aldehyde. 18) Provide the structure of the major organic product (s) in the reaction below. Get homework help and answers to your toughest questions in biology, chemistry, physics, math, calculus, engineering, accounting, English, writing help, business, humanities, and more. 3 Propose mechanisms to explain the observed products of alkene reactions. The starting material is (ch3)2C=NHch2ch3. D) 3-methyl-1-pentene. 24: Name the following amine, including R,S stereochemistry, and draw t 24. 119) Which of the following is a correct statement considering thermodynamic versus kinetic control of organic reactions? A) When a reaction is under thermodynamic control, the relative amounts of products depend on the activation energies of the steps leading to their formation. What is the major organic product obtained in the following reaction? A. B) 4-methyl-1-pentene. In case two or more stereoisomers are formed, label their relationship as diastereomers, enantiomers, structural isomers, or conformers. Predict the organic products of the following reaction. Answer to: Predict the organic product of the following reaction. Here the authors show that. Predict the MAJOR product of the following reaction. Question: Predict the organic products from reaction of 2-pentyne with H2O, H2SO4, HgSO4. (aq) (aq) PREDICTING REACTION PRODUCTS: DOUBLE REPLACEMENT REACTIONS Using a SOLUBILITY TABLE: Both reactants are soluble SO REACTION OCCURS. CuSO4 + H2SO4= no reaction Copper is below hydrogen in the metal activity series, meaning it doesn't normally displace hydrogen from acids (it can react to some degree with some acids). Ans: Mechanism Topic: Preparation of Ethers Section: 14. Assuming that the questioner intended capital letters for the chemical formulas specified, this equation is H2SO4 + 2 NaOH -> Na2SO4 + 2 H2O. Predict the product for the following reaction. H2 + Lindlar catalyst only reduces the alkyne to a cis-alkene. The products are salt and water. Other alkenes react in just the same way. Organic Chemistry, 6th Ed. If a chiral carbon atom is attached to a hydrogen atom, you should not show the hydrogen atom but use either a wedge or dashed bond and two sticks to establish stereochemistry where appropriate. The classical approach uses oxidation numbers and many chemists cannot imagine any way to find the solution other than balancing half-reactions for the process. Predicting the Products of an SN1/SN2/E1/E2 Competition When I teach nucleophilic substitution and elimination reactions, I find that students typically have very little trouble drawing each mechanism and predicting the products, so long as they are specifically told which reaction. When appropriate, be sure to indicate stereochemistry. Mechanism for the Dehydration of Alcohol into Alkene. Draw the major organic product formed in the following reaction. Fill in the reagents in their respective boxes above the arrows for the following reactions. Predict the major products for each. Chemistry Organic GOC Reaction Mechanism Elimination E1 E2 E1cB Elimination reactions Alkyl halides E1 vs E2 Saytzev Rule Zaitsev Rule. 79) 80)Provide the major organic product of the. The acid-catalyzed dehydration of trans-2-methylcyclohexanol yields 1methylcyclohexene as the major product. 40) Draw the major organic product generated in the reaction below. Indicate the stereochemistry, including H\'s, at each stereocenter. Indicate the structure of the major organic product in each of the following reactions. 40M NaOH are need to neutralize 30. If a chiral carbon atom is attached to a hydrogen atom, you should not show the hydrogen atom but use either a wedge or dashed bond and two sticks to establish stereochemistry where appropriate. My problem is that I do not understand what the products will be, and I am unsure why. 9cm}$ The answer however states that product (2) is the major product. NaOCH3 H3C CH3OH Cl H3C 13) Predict the most likely mechanism and the product from the reaction between 2-chloro-2-methylpentane and sodium ethoxide in ethanol. 7 39) Provide the major organic product of the following reactions. pdf), Text File (. Here is a list of topics: 1. The hydrolysis involves several steps, of which the slowest is the formation of a. 55)Provide the structure of the major organic product in the following reaction. Google Classroom Facebook Twitter. Zn + H2SO4 (. Different types of alcohols may dehydrate through a slightly different mechanism pathway. (14 pt) Draw the organic product expected from each of the following reactions. The primary reaction types students encounter are displacement, acid-base and combustion. Calculate H of this reaction per mole of H2SO4 and KOH reacted. Predicting the substitution and elimination products of a reaction can then be organized by the type of alkyl halide, as shown in Figure 8. Elimination reaction is done according to Zaitsev's rule. 2-butene HBr 2-butene HBr hydrobromic acid H Br-Br H b. The one-step mechanism is known as the E2 reaction The two-step mechanism is known as the E1 reaction. Concepts and reason The addition of halogens in ordinary temperature, in the absence of exposure to UV light to yield vicinal dihalides. There are mainly five types of organic reactions: In a substitution reaction, one atom or a group of atoms is substituted by another atom or a group of. ) click H3C CH-CH3+HI. Sample Problem 8. After this time, an excess of D2O was added. Chemistry Organic GOC Reaction Mechanism Elimination E1 E2 E1cB Elimination reactions Alkyl halides E1 vs E2 Saytzev Rule Zaitsev Rule. * Study and know the good leaving group ( important). Brz H2O Ye Boh OH HO Br A) I B) II C) III D) IV Predict the major product of the following reaction. Organic chemistry reaction question given diels-alder product, ID diene and dien Help draw the major product with the correct stereochemistry. O Cl CH3 NO2 F3C Br H NaNH2/NH3 H2O H2O O HO CH 3 NO2 HO Cl O HO CH 3 NO2 F3C NH2 F3C NH 2 F3C F3C NH2 F3C NH 2 a) dil. Show all organic products – if two or more products form, indicate the major product. 5)Provide the structure of the major organic product in the reaction below. Secondary organic aerosols are important contributors to the Earth’s radiation budget, however questions remain about their formation from highly-oxidized precursors. 26d: Propanone could also be formed from propene by reaction with steam over an acidic catalyst, 13N. CH3CH2CH2OH + H2SO4 --> H2O CH3CH2CH2-OSO2-OH propyl hydrogen sulphate. Draw your answer in skeletal form. (10 points) Predict the major organic product or products for each of the following. As such, bond dissociation energies are imperfect indicators of energy changes in a reaction. Product formation is undergone with the help of an elimination reaction. Identify the family (type) of each organic compound and write its IUPAC name. Assume planarity of the π network. 58)Provide the structure of the major organic product(s) in the following reaction. When appropriate, be sure to indicate stereochemistry. (a) (R)@[email protected]@ol + TsCl in pyridine (b) (S)-2-butyl tosylate + NaBr (c) cyclooctanol + NaOCl>HOAc (d) cyclopentylmethanol + CrO3 # pyridine # HCl (e) cyclopentylmethanol + Na2Cr2O7>H2SO4 (f) cyclopentanol + HCl>ZnCl2 (g) [email protected] + HBr (h) cyclooctylmethanol + CH3CH2MgBr (i. 37 A C 8 H 14 hydrocarbon (X) is reduced by sodium in liquid ammonia to a single C 8 H 16 product (Y). The product is tetrahydrofuran (THF), shown below: 12. If you can't find your institution, please check your spelling and do not use abbreviations. 2NaOH(aq) + H2SO4 (aq. Hydration of alkynes: Alkynes undergo acid catalyzed hydration in the presence of mercuric sulfate to give. Consider its structure to answer the following questions. 3 Propose mechanisms to explain the observed products of alkene reactions. Predict the products of the following reaction: CH3CH2OH + HCOOH → Predict the Products of Organic Reactions 002 Writing and Balancing Reactions Predicting Products - Duration:. Cl O Me 1) HNO3, H2SO4 2) NaOH Me Me SO3, H2SO4 a) b) c) d) O Me. Write equations, using displayed formulae, for the following reactions: a) ethyl methanoate with conc. Questions and answers covering Chapter 9 (E1/E2 reactions) assigned by Dr. 21 Draw structural formulas for the products of each of the following reactions. This is important in predicting SN1/SN2 reactions down the road. pdf), Text File (. D) Enantiomers exhibit equal and opposite optical rotations. Provide a name for the compound below. Show stereochemistry clearly. Reducing workup. Let's use the neutralization of stomach acid ("HCl") by milk of magnesia ["Mg(OH)"_2] as an example. When appropriate, be sure to indicate stereochemistry. In step (2) the hydroxide ion is a negative electron pair donor and rapidly combines with the carbocation, forming the C-O bond in the alcohol product. Predict the two major organic products of the following reaction. CH2=CH-CH3 + H20 ---H2SO4---> A. Hydrolysis involving organic compounds may be illustrated by the reaction of water with an ester of a carboxylic acid; all such esters have the general formula RCO―OR′, in which R and R′ are combining groups (for example, if R and R′ both represent the methyl group, CH 3, the ester is methyl acetate). A section of the protein is shown below. If there is no reaction say NR. Predict the MAJOR product of the following reaction: 2,3-dimethylcyclohexanol + H 2 SO 4 A) B) C) D) E) Page 9 13. 56)Provide a series of synthetic steps by which p-methylanisole can be prepared from p-cresol. Further reaction of product B with. These reactions are: Explain why the different products result. if there is more than one major product, both may be drawn in the same box. 21 Draw structural formulas for the products of each of the following reactions. It is an equilibrium process. (i) In the boxes below, draw the structures of the zwitterions formed from this section of the protein. Reactants Reagents Products Help; Na2Cr2O7 H2SO4, H2O: Note: Oxidation of primary alcohols to carboxylic acids: Na2Cr2O7 H2SO4, H2O: Note: Oxidation of secondary alcohols to ketones: Na2Cr2O7 H2SO4, H2O: No Products Predicted. Predict the major organic products of the following reaction: E1 to give alkene, more substituted. what is/are the organic product(s) in the reaction below. Organic Reactions *(Not yet Posted) 7. 3) Predict the major organic product formed from each of the Claisen Condensation Reactions. 2-hexanol Na2Cr2O7 H2SO4, H2O 1-hexanol 2-chlorohexane O 2-hexanone O hexanal O hexanoic acid Get more help from Chegg Get 1:1 help now from expert Chemistry tutors. Background. Alkene is reaction with water in the presence of sulfuric acid, first step is proton ( H + ) addition to the double bond which forms carbocation (more stable carbocation) followed. 3) Predict the major organic product formed from each of the Claisen Condensation Reactions. When drawing hydrogen atoms on a carbon atom, either include all hydrogen atoms or none on that carbon atom, or your structure may be marked incorrect. Questions are typically answered within 1 hour. If you consult a pKa table§, then you will find that protonated organic alcohols typically have pKa values around -2, while H₃O⁺ has a pKa of -1. CCH HgSO4 H2SO4, H2O 20) Provide the structure of the major organic product(s) in the reaction sequence below. When appropriate, be sure to indicate stereochemistry. 6 illustrate how to apply the information in Figure 8. For each of the following double replacement reactions, determine what the products of each reaction will be. what is/are the organic product(s) in the reaction below. (CHDCH— COOH ether (CH3)2CH — I. Include hydrogen atoms in your structure. This means that the protonated alcohol is a slightly stronger acid and thus the. Draw the major organic product formed in the following reaction. Draw the major organic products; Draw the organic products of the following reaction. Provide a name for the compound below. NH2 02 The product of the reaction is a (n): semicarhazone O 2,4-dinitrophenylhydrazone O imine O oxime. Predict the products of the following reaction. Alkenes and Alkynes 9. org is added to your Approved Personal Document E-mail List under your Personal Document Settings on the Manage Your Content and Devices page of your Amazon account. Acid catalyzed hydration of alkenes: For this question, the sulfuric acid will react with water to give hydronium ion. C3H6 + O2 à 2. Draw the mechanis for the following reaction: HBr Br H 2C HBr H 3C + Br H 3C Br. Give a detailed, step-by-step mechanism for the production of this compound. Several alkyl halides, including. 535 M H2SO4 is added to 20. Predict the structures of A and B in the following reaction: The importance of sulfonate esters as intermediates in many substitution reactions cannot be overstated. b) sodium hydroxide. cyclohexene HCl cyclohexene HCl H Cl-H Cl c. Brz H2O Ye Boh OH HO Br A) I B) II C) III D) IV Predict the major product of the following reaction. 97) Predict the major organic product resulting from the following sequence of reactions. We can make a similar reasoning as above that such arrangement forms from the reaction between a C=C bond and Br2 in the presence of an alcohol, a group that also happens to be present in the starting material. This is called steric hindrance. o-formylbenzenesulfonic acid and p-formylbenzenesulfonic acid D. Predict the organic product of the following reaction and include hydrogen atoms in your structure. 3-bromo-3-isopropylpentane b. Ph OEt O 2 1. Consider its structure to answer the following questions. Predict the MAJOR product of the following reaction. Predict the positions of electrophilic attack that lead to the major nitration product(s). Oxidation and Reduction Summary: Terms that Describe Reaction Selectivity A regioselective reaction forms predominantly or exclusively one constitutional isomer A. Organic chemistry reaction question given diels-alder product, ID diene and dien Help draw the major product with the correct stereochemistry. The products of a double replacement reaction will be similar to the reactants: The anions, the second of the two ions that make up each compound, will be reversed in the product compounds. 24: Name the following amine, including R,S stereochemistry, and draw t 24. CHO HNO3 H2SO4. asked by will. Indicate regiochemistry and stereochemistry when relevant. What is the molecular formula for this natural product? 5. intramolecularly. Draw the correct structure of the expected product of the following reaction. An alkane is formed. Draw the answer in skeletal form. Draw the major organic product that is produced in the following reaction. Organic food does not offer special protection against cancer or any other disease. Markovnikov's rule is needed to predict the major organic product. Note: The numbers do not have to do with the number. Thank you for your assistance. Concepts and reason Alcohols undergo a dehydration reaction when the react with concentrated acids in the presence of heat. Be sure to indicate the proper stereochemical. Predict the major products for each. Answer to: Predict the organic product of the following reaction. The hydroxide ion is the nucleophile. 3 10 13 50 40 100 53 500 73 1,000 76 5,000 79 10,000 80 20,000 80. kinetic control over the progress of the reaction. * select the most electrophile and the most nucleophil site. 2 Predict the products of the reactions of alkenes, including the orientation of the reaction (regio-chemistry) and the stereochemistry. elimination reactions are either impossible, or reactions conditions have been adjusted in such a way that elimination reactions are suppressed. Include hydrogen atoms in your structure. = H2O + an ester CH3COOH + C2H5OH = C2H5OCOOCH3 +H2O, ethyl acetate. Study Guide for. Here we have to predict the major products of the following reactions. * Study and know the good leaving group ( important). NH2 02 The product of the reaction is a (n): semicarhazone O 2,4-dinitrophenylhydrazone O imine O oxime. However on 1 there is no reaction considering silver is scale down within the endeavor series that copper and lithium ( identical goes for 7). When KOC(CH3)3 is used instead, the less highly substituted alkene product predominates. An elimination reaction occurs when a reactant is broken up into two products. Solution 18P :Step 1:A resonance form is another. Further reaction of product B with. png 695×186 7. In contrast to the S N 1 reaction, the product of the E1 reaction is an alkene: the starting material has lost the elements of HCl, and the hybridization of the carbon originally bearing the chlorine atom has changed from sp 3 to sp 2. QOI 0809 -O- Name_____ Predict the products of the following reaction and give a reasonable mechanism for their formation. When you have predicted the products, balance the equation and use a solubility table (like pg. Draw your answer in skeletal form. R54 Appendix B in the Prentice Hall Text Book) to determine which of the products (if any) will precipitate (be insoluble). Please Help. Really, the only way to be good at this is to study and memorize organic reactions. How many moles of NaOH are needed to react completely with 37 mols of H2SO4? b. These reactions are: Explain why the different products result. The following data were obt ained: [A], micromolar V0, nmoles/min 0. The (R) or (S) designation for each stereocenter carbon atom is specified adjacent to the answer box, please draw the products accordingly. Et0H, EtONa, 60 oc 2a. 21 Draw structural formulas for the products of each of the following reactions. pKa values allow you to predict the equilibrium direction of acid-base chemical reactions for organic molecules. Provide a name for the compound below. 07 M KOH in a coffee-cup calorimeter at 23. 5 41) Provide the major organic product of the reaction shown below. While knowing the reaction is important, it is more so important to. Predict the product for the following reaction and provide a curved arrow mechanism for the formation of the product. I did not draw your product, but you can see the mechanism and thus predict the product yourself. 2) (16 points) Suggest a reaction mechanism for each of the following reactions that accounts for both products. Once prepared, the samples were placed in a thermocycler for PCR and subjected to the following conditions: 95 °C 1 min, followed by 30 cycles of 95 °C 1 min, 60 °C 1 min, 72 °C 1 min and a. Discovered independently by the Russian chemist Alexander Borodin in 1869 and by the French chemist Charles-Adolphe Wurtz in 1872, the reaction combines two carbonyl compounds (the original experiments used aldehydes) to form a new β-hydroxy carbonyl compound. Provide the two major organic products of the following reaction. What is the major organic product obtained in the following reaction? A. Aldehydes and Ketones Aldehydes Organic compounds with carbonyl groups on the end carbon all-trans-retinal Show all the oxidation steps in converting butane to 3-butenoic acid Organic HW Draw & name 3 different aldehydes & 3 ketones that are isomers of the aldehydes. 4) Each compound below undergoes a Dieckmann Condensation (Intramolecular Claisen). Predict the product(s) for each of the following reactions. Ma 1) CH3MgCl (excess) Et20 2) H30 Complete the mechanism for the above reaction below. Consider the following substitution reaction, for example. In this reaction, the water molecule will behave like a hydrogen halide to the alkene which gives the addition product this reaction is known as a hydration reaction. Predict the product of the following reaction. Predict the products of the following reaction: CH3CH2OH + HCOOH → Predict the Products of Organic Reactions 002 Writing and Balancing Reactions Predicting Products - Duration:. Concepts and reason Michael Reaction The Michael reaction or Michael addition is the organic reaction in which a carbanion as in the form of an enolate ion adds to an via conjugated addition, resulting in the formation of new carbon-carbon single bond between the Michael donor and the Michael acceptor, giving the. If more than one product is possible, indicate which would be the major product. Identify the two products by writing accurate structures for each. png 778×457 26. The pKa is derived from the equilibrium constant for the acid's dissociation reaction, Ka, and uses a logarithmic scale to allow the pKa values to […]. Ozonolysis of Y (H 2 O 2 workup) produces two compounds: a two carbon carboxylic acid, and a four carbon ketone. Predicting the substitution and elimination products of a reaction can then be organized by the type of alkyl halide, as shown in Figure 8. A) I B) II C) III D) IV E) none of these. For each of the following double replacement reactions, determine what the products of each reaction will be. Thank you for your assistance. Tip: see chapter 6 of your textbook to learn what makes a good nucleophile or a good leaving group. d) Propanal. Describe the major organic product(s) of this reaction. For the following reaction, select a correct product characterization from the response list. png 778×457 26. Predict the product for the following reaction. Step-1 (a) 2,4-dinitrochlorobenzene + NaOCH3 + NaOCH3 In this reaction 2,4-dinitrochlorobenzene will react with sodium methoxide (NaOCH3) to form 2,4-dinitromethoxybenzene as a major product along with sodium chloride (NaCl). pdf), Text File (. For many college students, the phrase “organic chemistry” evokes angst and worry, as the subject can seem daunting to. Offer an explanation. Find the training resources you need for all your activities. com - View the original, and get the already-completed solution here!. Predict the product of the following reaction and include hydrogen atoms in your structure: Learn this topic by watching Acid-Catalyzed Hydration Concept Videos All Organic Chemistry Practice Problems Acid-Catalyzed Hydration Practice Problems. And we don't have any charge here, so it's in a neutral state. First of all, an elimination reaction is a type of organic reaction in which two substituents are removed from a molecule in either a one or two-step mechanism. (NYSE:CTLT) Q3 2020 Earnings Conference Call May 5, 2020 08:15 ET Company Participants Paul Surdez - Vice President, Investor Relations John Chim. BH 3; followed by H 2O 2, NaOH b. Draw the major organic product formed in the following reaction. These reactions proceed via an E2 and. Depending on the work up, different products may be isolated: reductive work-up gives either alcohols or carbonyl compounds, while oxidative work-up leads to carboxylic acids or ketones. Draw all stereoisomers that are formed. Their unprecedented degree of tunability gives MOFs the.